Green Energy & Environment

Volume 7, Issue 6

Green Energy & Environment 2022年第七卷第六期已正式出版。本期共收录文章24篇，其中research highlight 1篇，review article 3篇，research paper 20篇。欢迎大家阅读、下载和投稿！

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封面文章

北京化工大学孟洪教授、范红玮副教授与江南大学董亮亮副教授合作综述——Sprayed separation membranes: A systematic review and prospective opportunities（喷涂技术助力高性能分离膜的构筑与发展）。

该图以中国锦鲤为主题，锦鲤吐水代表喷涂技术构筑分离膜的核心内容；黄色和红色的小球代表喷涂膜的高效分离性能；锦鲤、大山和河水，寓意“鲤鱼跃龙门”，旨在突出喷涂技术在高性能分离膜制备领域的独特性和创新性。该研究不仅评估了当前喷涂分离膜的制备机理和研究态势，也指明了喷涂分离膜的未来发展方向，为下一代高性能喷涂分离膜的制备提供了有意参考。

封底文章

河南大学王丽/张敬来教授团队研究论文——Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure（双离子咪唑盐在常温常压下促进二氧化碳转化为环状碳酸酯）。

该图以海洋和天空为背景，图中大水泡中蓝色立方体代表离子液体的阳离子，橘色球体代表阴离子，阴阳离子通过相互作用力连接在一起。小水泡中为引入的亲CO₂基团，它的存在使离子液体具备了吸附二氧化碳的能力，从而可以在温和条件下催化二氧化碳转化为环状碳酸酯。该研究为开发能够在温和条件下催化CO₂的环加成反应的离子液体提供了新思路。本封面作品为庆祝河南大学建校110周年特别设计作品，校门巍峨挺拔，象征着河大人开创更美好未来的坚定信心！

Contents

Research highlight

Designing gradient solid electrolyte interphase for stable lithium metal batteries

Wenjing Deng, Xiaolei Wang*

https://doi.org/10.1016/j.gee.2021.12.005

Citation: W. Deng, X. Wang, Green Energy Environ. 7 (2022) 1129-1131.

Review articles

Direct conversion of methane to methanol by electrochemical methods

Haomin Jiang¹, Luting Zhang¹, Zhiwei Han, Yang Tang, Yanzhi Sun, Pingyu Wan, Yongmei Chen*, Morris D. Argyle, Maohong Fan

The direct conversion of methane to methanol by electrochemical methods maybe an alternative pathway to use natural gas, shale gas, and combustible ice resources. This mini-review focuses on the challenges of electrochemical methane conversion to methanol by summarizing the design strategies and the conversion effects reported in the literature.

https://doi.org/10.1016/j.gee.2021.11.007

Citation: H. Jiang, L. Zhang, Z. Han, Y. Tang, Y. Sun, P. Wan, Y. Chen, M.D. Argyle, M. Fan, Green Energy Environ. 7 (2022) 1132-1142.

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北京化工大学陈咏梅教授课题组GEE综述：电化学直接转化甲烷制甲醇

Sprayed separation membranes: A systematic review and prospective opportunities

Guangjin Zhao, Wenjing Han, Liangliang Dong*, Hongwei Fan*, Zhou Qu, Jiahui Gu, Hong Meng*

The progress in separation membranes using the spray technique, including the fundamentals, important features, applications, present challenge and future consideration, is summarized.

https://doi.org/10.1016/j.gee.2022.04.001

Citation: G. Zhao, W. Han, L. Dong, H. Fan, Z. Qu, J. Gu, H. Meng, Green Energy Environ. 7 (2022) 1143-1160.

Magic of hydrogen spillover: Understanding and application

Haifang Shen, Hao Li*, Zhensheng Yang, Chunli Li

The application of hydrogen spillover effect in hydrogen storage and catalysis was comprehensively summarized.

https://doi.org/10.1016/j.gee.2022.01.013

Citation: H. Shen, H. Li, Z. Yang, C. Li, Green Energy Environ. 7 (2022) 1161-1198.

Research papers

Novel design and synthesis of 1D bamboo-like CNTs@Sn₄P₃@C coaxial nanotubes for long-term sodium ion storage

Qianyu Zhang, Yuling Xu, Lifeng Qiu, Axue Liu, Rui Wang, Longhai Zhang, Chaofeng Zhang*, Yan-Jie Wang*, Jiujun Zhang*

Novel bamboo-like carbon nanotubes@Sn₄P₃@carbon coaxial nanotubes are sucessfully prepared using a newly developed hydrothermal method followed by a phophidation process, which can serve as advanced anode with excellent reversible capacity and a long cycling in sodium ion storage.

https://doi.org/10.1016/j.gee.2021.01.013

Citation: Q. Zhang, Y. Xu, L. Qiu, A. Liu, R. Wang, L. Zhang, C. Zhang, Y.-J. Wang, J. Zhang, Green Energy Environ. 7 (2022) 1199-1205.

Poly(thiourea triethylene glycol) as a multifunctional binder for enhanced performance in lithium-sulfur batteries

Luke Hencz, Hao Chen, Zhenzhen Wu, Xingxing Gu*, Meng Li, Yuhui Tian, Su Chen, Cheng Yan, Abdulaziz S.R. Bati, Joseph G. Shapter, Milton Kiefel, Dong-Sheng Li, Shanqing Zhang*

Poly(thiourea triethylene glycol) PTTG polymer used as a lithium-sulfur battery (LSB) binder shows strong chemical interaction with soluble polysulfides. Sulfur-PTTG cathodes possess high electronic and ionic conductivity as well as robust mechanical properties to provide excellent LSB performance.

https://doi.org/10.1016/j.gee.2021.01.014

Citation: L. Hencz, H. Chen, Z. Wu, X. Gu, M. Li, Y. Tian, S. Chen, C. Yan, A.S.R. Bati, J.G. Shapter, M. Kiefel, D.-S. Li, S. Zhang, Green Energy Environ. 7 (2022) 1206-1216.

Deep eutectic solvent strategy enables an octahedral Ni–Co precursor for creating high-performance NiCo₂O₄ catalyst toward oxygen evolution reaction

Chenyun Zhang, Bingwei Xin, Tingting Chen, Hao Ying, Zhonghao Li*, Jingcheng Hao

An innovative DES strategy was proposed for synthesizing water-sensitive NiCo–NH₃ complex precursor, which was effectively converted into NiCo₂O₄ nanooctahedrons via thermal decomposition, realizing a high-performance OER electrocatalyst.

https://doi.org/10.1016/j.gee.2021.01.017

Citation: C. Zhang, B. Xin, T. Chen, H. Ying, Z. Li, J. Hao, Green Energy Environ. 7 (2022) 1217-1227.

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山东大学李钟号教授团队：基于低共熔溶剂的钴镍含氨配合物的设计及其制备NiCo₂O₄析氧催化剂的研究

Engineered NiCo-LDH nanosheets- and ZnFe₂O₄ nanocubes-decorated carbon nanofiber bonded mats for high-rate asymmetric supercapacitors

Jae-Gyoung Seong, Tae Hoon Ko*, Danyun Lei, Woong-Ki Choi, Yun-Su Kuk, Min-Kang Seo, Byoung-Suhk Kim*

The coreeshell NiCo-LDH nanosheet- and ZnFe₂O₄ nanocube-decorated carbon nanofiber composites with bonded network structure as cathode and anode electrode materials were prepared. The fabricated supercapacitor device delivered a specific capacitance of ~98 F g^-1 at 1 A g^-1 and excellent capacitance retention of ~88% after 5000 charge-discharge cycles.

https://doi.org/10.1016/j.gee.2021.01.015

Citation: J.-G. Seong, T.H. Ko, D. Lei, W.-K. Choi, Y.-S. Kuk, M.-K. Seo, B.-S. Kim, Green Energy Environ. 7 (2022) 1228-1240.

Enhancing the side-chain alkylation of toluene with methanol to styrene over the Cs-modified X zeolite by the assistance of basic picoline as a co-catalyst

Zhe Hong, Guoqing Zhao, Fangtao Huang, Xiaoxia Wang, Zhirong Zhu*

The addition of suitable amount of 2-picoline facilitated the activity for toluene side-chain alkylation on Cs-modified zeolite catalyst.

https://doi.org/10.1016/j.gee.2021.01.020

Citation: Z. Hong, G. Zhao, F. Huang, X. Wang, Z. Zhu, Green Energy Environ. 7 (2022) 1241-1252.

Boosting rate and cycling performance of K-doped Na₃V₂(PO₄)₂F₃ cathode for high-energy-density sodium-ion batteries

Jiexin Zhang¹, YangYang Lai¹, Peng Li, Yanxia Wang, Faping Zhong, Xiangming Feng, Weihua Chen, Jianjun Liu, Xinping Ai, Hanxi Yang, Yuliang Cao*

A novel cathode, K doped Na₃V₂(PO₄)₂F₃ is synthesized by a facile ball-milling method. With the structural advantages and the suitable K doping site, the K-doped Na₃V₂(PO₄)₂F₃ cathode exhibits enhanced sodium storage performance in terms of high specific capacity, excellent rate capability, and superior cycling stability.

https://doi.org/10.1016/j.gee.2021.01.001

Citation: J. Zhang, Y. Lai, P. Li, Y. Wang, F. Zhong, X. Feng, W. Chen, J. Liu, X. Ai, H. Yang, Y. Cao, Green Energy Environ. 7 (2022) 1253-1262.

Enhancing sintering resistance of atomically dispersed catalysts in reducing environments with organic monolayers

Jing Zhang, Chithra Asokan, Gregory Zakem, Phillip Christopher*, J. Will Medlin*

Methyl phosphonic acid monolayers suppress the migration of isolated Rh atoms on metal oxide supports, improving catalyst thermal stability under reducing conditions.

https://doi.org/10.1016/j.gee.2021.01.022

Citation: J. Zhang, C. Asokan, G. Zakem, P. Christopher, J.W. Medlin, Green Energy Environ. 7 (2022) 1263-1269.

Converting furfural residue wastes to carbon materials for high performance supercapacitor

Xiaoying Guo, Xusheng Zhang, Yingxiong Wang, Xiaodong Tian*, Yan Qiao*

Furfural residues-derived porous carbon with excellent electrochemical performance was prepared by changing components.

https://doi.org/10.1016/j.gee.2021.01.021

Citation: X. Guo, X. Zhang, Y. Wang, X. Tian, Y. Qiao, Green Energy Environ. 7 (2022) 1270-1280.

Ferric acetylacetonate/covalent organic framework composite for high performance photocatalytic oxidation

Mingzhao Xu, Lifei Liu, Jianling Zhang*, Fanyu Zhang, Gang Chen, Qiang Wan, Yufei Sha, Xiuyan Cheng, Zhuizhui Su

Here, we synthesized Fe(acac)₃/Bp-COF composite photocatalyst in one step under mild conditions. Compared with Bp-COF, composite photocatalyst has facile preparation and exhibits highly improved light absorbance and transformation of photogenerated electronehole pairs. The composite photocatalyst can efficiently convert benzyl alcohol into benzaldehyde under the condition of room temperature and air as oxidant without producing other by-products.

https://doi.org/10.1016/j.gee.2021.02.001

Citation: M. Xu, L. Liu, J. Zhang, F. Zhang, G. Chen, Q. Wan, Y. Sha, X. Cheng, Z. Su, Green Energy Environ. 7 (2022) 1281-1288.

Manganese doping to boost the capacitance performance of hierarchical Co₉S₈@Co(OH)₂ nanosheet arrays

Lingxia Zheng, Weiqing Ye, Pengju Yang, Jianlan Song, Xiaowei Shi, Huajun Zheng*

The introduction of Mg dopants endows tuned electronic structure of Co₉S₈@Co(OH)₂ nanosheets and enhanced interfacial activities as well as facilitated reaction kinetics, leading to ultrahigh capacity and outstanding long-term stability. The encouraging results might offer an effective strategy to optimize the electrodes for high-performance energy-storage devices.

https://doi.org/10.1016/j.gee.2021.02.002

Citation: L. Zheng, W. Ye, P. Yang, J. Song, X. Shi, H. Zheng, Green Energy Environ. 7 (2022) 1289-1297.

Disposal methods for used passenger car tires: One of the fastest growing solid wastes in China

Biaohua Chen, Dahai Zheng, Ruinian Xu*, Shuai Leng, Lili Han, Qianqian Zhang, Ning Liu, Chengna Dai, Bin Wu, Gangqiang Yu, Jie Cheng

Waste tire generation and disposal methods in China were investigated. Tire retreading and tire rubber reclaiming had no longer sufficient to recycle those waste tires. Pyrolysis technology is regarded as a promising way to solve this fast increasing solid wastes.

https://doi.org/10.1016/j.gee.2021.02.003

Citation: B. Chen, D. Zheng, R. Xu, S. Leng, L. Han, Q. Zhang, N. Liu, C. Dai, B. Wu, G. Yu, J. Cheng, Green Energy Environ. 7 (2022) 1298-1309.

Biomass-based N doped carbon as metal-free catalyst for selective oxidation of D-xylose into D-xylonic acid

Zengyong Li, Yiming Huang, Xiao Chi, Di Li, Linxin Zhong, Xuehui Li, Chuanfu Liu*, Xinwen Peng*

A defect-rich N doped carbon catalyst exhibits high catalytic activity for selective oxidation of D-xylose into D-xylonic acid. With graphitic N as the intrinsic active sites, D-xylonic acid yield of 57.4% could be obtained.

https://doi.org/10.1016/j.gee.2021.01.004

Citation: Z. Li, Y. Huang, X. Chi, D. Li, L. Zhong, X. Li, C. Liu, X. Peng, Green Energy Environ. 7 (2022) 1310-1317.

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华南理工大学彭新文教授：生物质氮掺杂炭催化木糖选择性制备木糖酸

A new perspective on polyethylene-promoted lignin pyrolysis with mass transfer and radical explanation

Yuyang Fan¹, Chao Liu¹, Xiangchen Kong, Yue Han, Ming Lei*, Rui Xiao*

Mass transfer and radical reactions together controlled the co-pyrolysis of lignin and PE. Good mass transfer in layered lignin/PE co-pyrolysis approach promoted the radical quenching reactions and favored the formation of lignin-derived phenols.

https://doi.org/10.1016/j.gee.2021.02.004

Citation: Y. Fan, C. Liu, X. Kong, Y. Han, M. Lei, R. Xiao, Green Energy Environ. 7 (2022) 1318-1326.

Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure

Tengfei Wang¹, Danning Zheng¹, Beibei An, Yi Liu, Tiegang Ren, Hans Ågren, Li Wang*, Jinglai Zhang*, Mårten S.G. Ahlquist*

A novel dual-ionic imidazolium salt displays the excellent catalytic activity for cycloaddition of carbon dioxide and epoxides at ambient temperature and CO₂ pressure under solvent free conditions without any additional catalysts.

https://doi.org/10.1016/j.gee.2021.02.011

Citation: T. Wang, D. Zheng, B. An, Y. Liu, T. Ren, H. Ågren, L. Wang, J. Zhang, M.S.G. Ahlquist, Green Energy Environ. 7 (2022) 1327-1339.

点击下方标题查看中文解读：

河南大学王丽/张敬来教授团队GEE：双离子咪唑盐在常温常压下促进二氧化碳转化为环状碳酸酯

Enhanced catalytic conversion of polysulfides using high-percentage 1T-phase metallic WS₂ nanosheets for Li-S batteries

Changyu Yang, Ning Gong, Tao Chen, Yang Li, Wenchao Peng, Fengbao Zhang, Xiaobin Fan*

The conversion mechanism of S on the surface of 1T-WS₂ and 2H-WS₂ in Li-S battery.

https://doi.org/10.1016/j.gee.2021.03.001

Citation: C. Yang, N. Gong, T. Chen, Y. Li, W. Peng, F. Zhang, X. Fan, Green Energy Environ. 7 (2022) 1340-1348.

Pt-Pd bimetallic nanoparticles anchored on uniform mesoporous MnO₂ sphere as an advanced nanocatalyst for highly efficient toluene oxidation

Jiaqin He, Dongyun Chen*, Najun Li, Qingfeng Xu, Hua Li, Jinghui He, Jianmei Lu*

Uniform mesoporous MnO₂ nanosphere-supported bimetallic Pt-Pd nanoparticles were successfully fabricated using hard templates for the total catalytic degradation of volatile organic compounds at low temperature. The introduction of mesopores into the MnO₂ support induces a large specific surface area and pore size, thus providing numerous accessible active sites and enhanced diffusion properties. Moreover, the addition of a secondary noble metal can adjust the O_ads/O_latt molar ratios, resulting in high catalytic activity.

https://doi.org/10.1016/j.gee.2021.03.002

Citation: J. He, D. Chen, N. Li, Q. Xu, H. Li, J. He, J. Lu, Green Energy Environ. 7 (2022) 1349-1360.

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苏州大学路建美教授团队：铂钯双金属纳米颗粒锚定在均匀介孔二氧化锰球上作为高效甲苯催化氧化的先进纳米催化剂

Green and selective hydrogenation of aromatic diamines over the nanosheet Ru/g–C₃N₄–H₂ catalyst prepared by ultrasonic assisted impregnation-deposition method

Huanhuan Yang, Liguo Wang*, Shuang Xu, Yan Cao, Peng He, Jiaqiang Chen, Zheng Zheng, Huiquan Li*

Nanosheet g-C₃N₄-H₂ was derived from thermal exfoliation of bulk g-C₃N₄ under hydrogen atmosphere, then a green catalyst with ultrafine Ru species supported on the nanosheet g-C₃N₄-H₂ was prepared by facile ultrasonic assisted impregnation-deposition method and the Ru/g-C₃N₄-H₂ catalyst displayed excellent performance towards selective hydrogenation of aromatic diamines to alicyclic diamines without any alkaline additives.

https://doi.org/10.1016/j.gee.2021.01.003

Citation: H. Yang, L. Wang, S. Xu, Y. Cao, P. He, J. Chen, Z. Zheng, H. Li, Green Energy Environ. 7 (2022) 1361-1376.

Double Z-Scheme g-C₃N₄/BiOI/CdS heterojunction with I₃^—/I^— pairs for enhanced visible light photocatalytic performance

Yan Zhang, Yixiao Wu, Liang Wan, Wenfeng Yang, Huijun Ding, Chongyang Lu, Weihao Zhang*, Zipeng Xing*

Double Z-Scheme g-C₃N₄/BiOI/CdS heterojunction is fabricated through calcination, solvothermal and chemical bath deposition approaches, which exhibits excellent photocatalytic performances due to providing adequate surface active-sites, accelerating spatial charge separation, and enhancing visible light absorption.

https://doi.org/10.1016/j.gee.2021.08.004

Citation: Y. Zhang, Y. Wu, L. Wan, W. Yang, H. Ding, C. Lu, W. Zhang, Z. Xing, Green Energy Environ. 7 (2022) 1377-1389.

Electron promoted ZnO for catalytic synthesis of higher alcohols from syngas

Fang Li, Qian Zhang, Jing Liu, Nan Cui, Guoqing Guan, Wei Huang*

The band structure and Fermi level of ZnO can be electronically-modulated by adjusting Cu doping amount achieving a higher fraction of straight chain higher alcohols from syngas, which promoted the donor reaction for the formation of key intermediates CH_x species by enhancing thermally excited electron transfer.

https://doi.org/10.1016/j.gee.2022.01.015

Citation: F. Li, Q. Zhang, J. Liu, N. Cui, G. Guan, W. Huang, Green Energy Environ. 7 (2022) 1390-1400.

Ultrafast battery heat dissipation enabled by highly ordered and interconnected hexagonal boron nitride thermal conductive composites

Zhuoya Wang¹, Kaihang Zhang¹, Bing Zhang, Zheming Tong, Shulan Mao, Hao Bai, Yingying Lu*

A h-BN/PW composite with ordered and interconnected thermal network derived from ice template combined freeze-drying method shows excellent heat dissipation performance in the application for heat dissipation management of battery.

https://doi.org/10.1016/j.gee.2022.02.007

Citation: Z. Wang, K. Zhang, B. Zhang, Z. Tong, S. Mao, H. Bai, Y. Lu, Green Energy Environ. 7 (2022) 1401-1410.

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浙江大学陆盈盈教授团队GEE：h-BN/PW导热复合材料实现电池快速散热

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